| Tracklisting |
|---|
| CD 1 |
|---|
| 1. | First Season End Title - Jerry Goldsmith [1:16] |
| 2. | The Vulcan Affair Suite No. 2 - Jerry Goldsmith [9:59] |
| 3. | The Iowa-Scuba Affair - Morton Stevens [6:54] |
| 4. | The Shark Affair - Walter Scharf [7:55] |
| 5. | The Deadly Games Affair Suite No. 2 - Jerry Goldsmith [8:38] |
| 6. | Meet Mr. Solo - Jerry Goldsmith [1:45] |
| 7. | The Giuoco Piano Affair - Walter Scharf [3:23] |
| 8. | The King of Knaves Affair Suite No. 2 - Jerry Goldsmith [3:40] |
| 9. | First Season Main Title (Revised) - Jerry Goldsmith [0:56] |
| 10. | The Deadly Decoy Affair - Walter Scharf [4:32] |
| 11. | The Spy With My Face - Morton Stevens [5:12] |
| 12. | Second Season Main Title - Jerry Goldsmith [0:37] |
| 13. | Alexander the Greater Affair - Gerald Fried [1:25] |
| 14. | The Ultimate Computer Affair - Lalo Schifrin [5:00] |
| 15. | The Very Important Zombie Affair - Gerald Fried [4:10] |
| 16. | The Dippy Blonde Affair - Robert Drasnin [2:01] |
| 17. | The Deadly Goddess Affair - Gerald Fried [2:31] |
| 18. | The Moonglow Affair - Gerald Fried [7:09] |
| CD 2 |
|---|
| 1. | One of Our Spies Is Missing - Jerry Goldsmith [3:08] |
| 2. | Third Season Main Title - Jerry Goldsmith [0:31] |
| 3. | The Sort of Do-It-Yourself Dreadful Affair - Gerald Fried [6:39] |
| 4. | The Galatea Affair - Robert Drasnin [5:36] |
| 5. | The Pop Art Affair - Robert Drasnin [4:34] |
| 6. | The Come With Me to the Casbah Affair - Gerald Fried [4:16] |
| 7. | The Off-Broadway Affair - Gerald Fried [7:12] |
| 8. | The Concrete Overcoat Affair - Nelson Riddle [6:48] |
| 9. | The Napoleon's Tomb Affair - Gerald Fried [5:17] |
| 10. | Alternate Fourth Season Main Title - Jerry Goldsmith [0:37] |
| 11. | Fourth Season End Title - Jerry Goldsmith [0:36] |
| 12. | The Test Tube Killer Affair - Gerald Fried [7:05] |
| 13. | The Prince of Darkness Affair - Richard Shores [11:39] |
| 14. | The Seven Wonders of the World Affair - Richard Shores [11:46] |
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